On-site oxygen generation for biological H2S reduction, injecting pure O2 into your bioprocess without diluting the biogas with contaminants.
BiOXYGEN by SYSADVANCE makes use of the PSA technology to produce pure oxygen from air by selective adsorption of N2 on a special molecular sieve material.
As a result, only O2 is injected in your bioprocess for H2S reduction avoiding the biogas dilution with contaminants.
A special O2 injection system developed by SYSADVANCE use proportional valves injecting O2 as a function of external process variable such as the H2S content in the raw biogas, raw biogas flow or even a combination of both is available.
Oxygen production cost per Nm³ of biogas treated is extremely low, considering the benefits of its application.
SYSADVANCE offers a wide range of O2 injection systems (PSA and VSA) covering the needs for anaerobic digestion plants with production capacities between 20 Nm³/h and 2000 Nm³/h of raw biogas.
Reduction to sulphate (H2SO4) by O2 injection into the headspace of the digester (a rate of O2 corresponding 1% of the biogas is required).
Approximately 1% of O2 is charged to the column containing the immobilized microorganisms responsible for the degradation of the H2S to sodium sulphate (NaHSO4). Sulphuric acid is formed if the rate of air injected is reduced (also suitable for trickling filters).
H2S adsorption on catalyst impregnated activated carbon requires the presence of 0.5 – 1.0% of O2 in the presence of humidity to oxidizes H2S to elementary sulphur that binds to the adsorbent surface (also suitable for iron sponge filters).
Produce oxygen on-site and eliminate dependence on external suppliers and market price fluctuations.
Remove cylinder handling and simplify oxygen supply logistics and supplier management.
Operate with power consumption below 0.5 kWh/Nm³ at 90% oxygen purity.
Generate oxygen with purity levels up to 93% and a dew point below -50°C.
Scalable systems with skid-mounted or containerized configurations for easy integration and mobility.
Available with oxygen compression up to 8 barg to meet a wide range of process requirements.
Integrated oxygen sensor with remote monitoring capabilities for enhanced process control.
VSA technology available for higher flow rates with even lower energy consumption.
Adsorption Technology
Oxygen generators incorporate sets of columns filled with molecular sieve. Under pressure these columns retain all compounds present in air (Nitrogen, Carbon Dioxide and Water), which tie to the molecular sieve during the building of pressure, with the exception of the Oxygen. This process is known as PSA (Pressure Swing Adsorption) or VSA (Vacuum Swing Adsorption).
A modular system allows synchronized operation of several parallel units, in order to ensure a constant flow at the required purity.

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Energy Catalogue
Download BrochurePressure Swing Adsorption (PSA) separates gases by taking advantage of the different adsorption characteristics of gas molecules under pressure. As compressed gas enters an adsorbent vessel, unwanted components are retained on the adsorbent while the desired product gas passes through.When the adsorbent becomes saturated, the vessel is depressurized to release the captured gases and regenerate the adsorbent. Multiple vessels operate in sequence so that purification and regeneration occur simultaneously, providing a continuous supply of high-purity gas.
Talk to EngineerA PSA system automatically regulates pressure, cycle timing, and gas flow to achieve the required purity and production rate. Modern PLC-based control systems continuously monitor operating conditions and adjust the cycle parameters to maintain stable performance despite changes in demand and inlet biogas composition
Talk to EngineerTurndown refers to the range over which a PSA can reduce its production while maintaining the specified gas quality. Depending on the process design, many PSA systems can operate efficiently across a wide flow range without compromising product purity.
Talk to EngineerGas purity depends on feed gas composition, pressure, temperature, flow rate, and adsorption cycle timing. Once commissioned, the PSA is optimized for its design conditions, but operating parameters are self-adjusted if process conditions change.
Talk to EngineerThe adsorbent material depends entirely on the application. Common materials include activated alumina, silica gel, molecular sieves (zeolites), and activated carbon. The selection is based on the target gas separation, contaminant levels, and operating conditions.
Talk to EngineerUnder normal operating conditions, PSA adsorbents typically provide many years of reliable service. Their lifetime depends largely on feed gas quality and correct operation. Exposure to liquid contaminants, excessive particulate loading, or operation outside design limits can reduce adsorbent performance. On average, if no serious contamination occurs, adsorbent is expected to last more than 10yrs.
Talk to EngineerPSA technology is widely recognized for its high reliability because it contains relatively few moving parts. With routine preventive maintenance and correct operating conditions, plant availability typically exceeds 99%, making PSA suitable for continuous industrial operation.
Talk to EngineerCommissioning time depends on system size and complexity. Smaller packaged systems are often operational within a few days, while larger industrial installations generally require one to two weeks, including testing, optimization, and operator training.
Talk to EngineerThe main operating costs are electricity for compressors and controls, routine maintenance, and periodic replacement of filters or consumable components. Since PSA systems require no chemical regenerants, operating costs are generally predictable and comparatively low.
Talk to EngineerRoutine maintenance generally includes replacing filter elements, inspecting valves and instrumentation, checking control systems, and performing scheduled servicing of rotating equipment where applicable. Following the manufacturer's maintenance schedule helps ensure long-term reliability.
Talk to EngineerElectrical requirements vary depending on system size and customer standards. PSA systems are available for a wide range of international voltages and frequencies and can be integrated with existing plant electrical infrastructure.
Talk to EngineerYes. Many PSA systems allow cycle parameters to be adjusted to accommodate moderate variations in feed gas composition, pressure, or required product purity. Significant process changes may require re-optimization by the equipment supplier.
Talk to EngineerResidual oxygen can create safety risks, increase corrosion and prevent compliance with gas grid specifications. METHAGEN VPSA directly removes oxygen without requiring a separate deoxygenation unit.
Talk to EngineerDepending on the application, oxygen levels as low as 0.2% can be achieved without additional DEOXO equipment.
Talk to EngineerDirect oxygen removal avoids additional deoxygenation equipment, reducing CAPEX, maintenance and OPEX, as well as to allow Oxygen injection in Biogas for H2S reduction.
Talk to EngineerYes. Oxygen may be injected upstream in the digestor or HsS filter system to improve H₂S removal while VPSA removes residual oxygen before grid injection, increasing efficiency in H2S reduction and decreasing costs associated with H2S pre-treatment.
Talk to EngineerNitrogen reduces biomethane calorific value and may prevent compliance with pipeline specifications.
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Talk to EngineerYes. The METHAGEN LF VPSA process is specifically designed for efficient nitrogen removal up to 20% Nitrogen.
Talk to EngineerMembranes separate CO₂ efficiently but have limited methane/nitrogen selectivity, thus not allowing for the removal of Nitrogen in Biogas..
Talk to EngineerNo. It is effective but generally requires higher energy consumption and more complex and costly equipment.
Talk to EngineerAutomatic control adjusts cycle time and feed flow to maintain stable product quality.
Talk to EngineerYes. Continuous process control maintains biomethane quality, independently from volatility in Biogas inlet composition.
Talk to EngineerVPSA is generally more tolerant of temporary contaminant excursions than membrane systems.
Talk to EngineerSiloxanes, VOCs, ammonia, liquid water, compressor oil and particulates.
Talk to EngineerVPSA is less likely to suffer permanent damage than membrane systems after temporary upsets.
Talk to EngineerLower energy consumption reduces lifetime operating costs.
Talk to EngineerSpecific energy consumption can be as low as approximately 0.18 kWh/Nm³ under suitable conditions.
Talk to EngineerReduced electricity consumption lowers OPEX throughout the project lifetime.
Talk to EngineerTypically after around 10 years or longer under normal operating conditions.
Talk to EngineerVPSA generally requires fewer replacement interventions, reducing lifecycle costs.
Talk to EngineerNo. It is a dry adsorption process.
Talk to EngineerYes, subject to local gas quality specifications, up to 99% CH4 concentration.
Talk to EngineerYes. It builds on SYSADVANCE's extensive PSA installation base.
Talk to EngineerApproximately 165 to 5,000 Nm³/h in modular configurations.
Talk to EngineerA PSA can be integrated into a plant control system using standard industrial communication protocols and conventional digital or analog I/O. The exact signal list depends on the level of automation and customer requirements.
Talk to EngineerMost PSA systems reach operating pressure within minutes and begin producing gas shortly afterward. Full design purity is typically achieved once the adsorption cycle has stabilized.
Talk to EngineerDuring an emergency stop, feed gas is isolated and the adsorption cycle stops safely. Once the cause has been resolved, the system can normally be restarted following the standard operating procedure. Extended shutdowns may require depressurization before restart.
Talk to EngineerYes. Industrial PSA systems are commonly designed for outdoor installation and can be supplied with weather protection, insulation, heat tracing, or other environmental features to suit local climate conditions.
Talk to EngineerHigher feed pressure generally improves adsorption efficiency and reduces equipment size, provided the system operates within its design limits. The optimum operating pressure depends on the gas composition and the required product specifications.
Talk to EngineerNeed technical advice? Our engineering team is ready to help you define the best solution for your application.
Daniel Esteves
Sales Executive Energy Division
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